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Amino acids connect when the carboxyl group of one reacts with another's amino group

The thiol group of glutathione chelates copper ions on the active site of enzyme tyrosinase thus inhibiting it

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[1] The term master antioxidant reflects two facts: glutathione directly neutralizes reactive oxygen species, and it also regenerates and supports other antioxidants (such as vitamins C and E) while serving as the substrate for a family of protective enzymes