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Nature 585 , 357362 (2020)

When licensed pharmacies can once again legally prepare these compounds, the quality difference becomes concrete and measurable not theoretical

Hopfner K-P, Hornung V

By the time most patients are in their late 30s or 40s, pineal calcification and reduced melatonin synthesis have already begun degrading sleep architecture, particularly the slow-wave deep sleep phases where cellular repair, growth hormone release, and memory consolidation occur

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They have experimentally shown vitamin D does activate the tryptophan-hydroxylase-2 gene and, uh that can affect serotonin