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These APX forms undergo structural and functional transitions between HMW and LMW forms

For the closely eluting VVVFIKPTC(GSH)PYC(O3)R and VVVFIKPTC(O3)PYC(GSH)R peptides, the abundance was determined by summing the area of the XIC of the 3 transitions that are unique to the peptides (VVVFIKPTC(GSSG)PYC(O3)R: m/z 939.433 ++ 326.113 [y2] + ,C(GSH), 489.176 [y3] + Y, and 586.229 [y4] + P, and VVFIKPTC(O3)PYC(GSH)R: ++ 538.196 [y2] + C(O3), 746.260 [y3] + Y, and 843.312 [y4] + P) (diagnostic ions are boxed in the ion tables in Supplementary Fig

Propionyl-CoA can be further converted into AA, fatty acids (FA) and TCA cycle intermediates ( Methionine scarcity impairs cancer cells' proliferation (55), and methionine dependency is controlled by PI3K/AKT/mTOR pathway through the induction of the expression of cyst(e)ine/glutamate antiporter xc- (xCT

Increased consumption of antioxidants was also reported for other members of the nonenzymatic antioxidant system, including -tocopherol and ascorbic acid (35, 86)

Investigation findings