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Free radicals are unstable molecules formed during intense exercise, PED use, toxin exposure, or even just from breathing

GSH is found in all mammalian tissues as the most abundant non-protein thiol that defends against oxidative stress and possess a distinctive stability provided by a -carboxyl bond within the molecule (Figure 1A)

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[DOI] [PMC free article] [PubMed] [Google Scholar] 122.Zhou W., Kalivas P.W

1985, 6: 165-10.1093/carcin/6.2.165

The anti conformation is preferred in tertiary S-nitrosothiols due to steric hindrance from the bulky carbon substituents [21]