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Either pathway alters the peptide structure and potentially its biological activity

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The route affects administration technique only, not peptide stability or preparation

Alpha lipoic acid (ALA), also known as thioctic acid, is an endogenous organosulfur compound that is naturally synthesized in small amounts within the mitochondria of human cells

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Note that formation of a second possible inter-chain salt bridge, between the N-terminus of the L-peptide and the C-terminus of the DRI-peptide is less likely as the first (last) 10 residues in the L(DRI-)peptide are flexible and do not adopt a defined structure