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7a, 11b, 12a,c and 14a were created using BioRender ( Ethics declarations Competing interests J.M.M

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In contrast, for elements at the higher affinity end of the Irving-Williams series the binding affinities are such that there is no free (hydrated) metal present, and protein metalation involves ligand-exchange reactions between small molecule ligands or protein chaperones and nascent metalloproteins (Foster et al., 2022)